Author(s):
1. Ljubica Brenjo, Prirodno-matematički fakultet, Univerzitet u Novom Sadu, Trg Dositeja Obradovića 3, Novi Sad, Srbija, Serbia
2. Olivera Klisurić, University of Novi Sad, Faculty of Sciences, Department of Physics, Trg Dositeja Obradovića 4, Novi , Serbia
3. Jovica Nešić, Vojnotehnički institut, Ratka Resanovića 1, Beograd, Srbija, Serbia
4. Niko Radulović, Prirodno-matematički fakultet, Univerzitet u Nišu, Višegradska 33, Niš, Srbija, Serbia
5. Srđan Bjedov, Prirodno-matematički fakultet, Univerzitet u Novom Sadu, Trg Dositeja Obradovića 3, Novi Sad, Srbija, Serbia
6. Aleksandar Oklješa, Prirodno-matematički fakultet, Univerzitet u Novom Sadu, Trg Dositeja Obradovića 3, Novi Sad, Srbija, Serbia

Abstract:
The development of modern energetic materials (EM) is a significant area of materials science research. Azidoximes are compounds that are attractive as potential EM because they contain the energetic azide group, and possess an oxygen atom from the oxime, which contributes to a better oxygen balance. They are usually used as precursors for the corresponding N-hydroxytetrazoles. These tetrazole derivatives contain, aside from a high nitrogen content, planarity, and high heat of formation, an oxygen atom in their structure, which results in a more positive oxygen balance. In contrast to tetrazoles, azidoximes are insufficiently researched as potential EM. In this work, the synthesis of (1Z,2E)-3-amino-N'-hydroxy-2-(hydroxyimino)-3-oxopropanimidoyl azide is described. The structure of the compound was confirmed by IR and NMR spectroscopy, and by single-crystal X-ray diffraction. Physicochemical parameters were obtained via theoretical calculations. Non-covalent interactions in the crystal were analyzed as well.

Key words:
Energetic materials,tetrazoles,azidoximes

Thematic field:
SYMPOSIUM A - Science of matter, condensed matter and physics of solid states

Date of abstract submission:
27.06.2025.

Conference:
Contemporary Materials 2025 - Savremeni Materijali

Abstract